Sunday, August 26, 2018

OXIDASITION AND REDUCTION REACTION

DEFINITIONS OF OXIDATION AND REDUCTION (REDOX)

This page looks at the various definitions of oxidation and reduction (redox) in terms of the transfer of oxygen, hydrogen and electrons. It also explains the terms oxidising agent and reducing agent.

Oxidation and reduction in terms of oxygen transferDefinitions
  • Oxidation is gain of oxygen.
  • Reduction is loss of oxygen.
For example, in the extraction of iron from its ore:
Because both reduction and oxidation are going on side-by-side, this is known as a redox reaction.
Oxidising and reducing agents
An oxidising agent is substance which oxidises something else. In the above example, the iron(III) oxide is the oxidising agent.
A reducing agent reduces something else. In the equation, the carbon monoxide is the reducing agent.
  • Oxidising agents give oxygen to another substance.
  • Reducing agents remove oxygen from another substance.

Oxidation and reduction in terms of hydrogen transferThese are old definitions which aren't used very much nowadays. The most likely place you will come across them is in organic chemistry.
Definitions
  • Oxidation is loss of hydrogen.
  • Reduction is gain of hydrogen.
Notice that these are exactly the opposite of the oxygen definitions.
For example, ethanol can be oxidised to ethanal:
You would need to use an oxidising agent to remove the hydrogen from the ethanol. A commonly used oxidising agent is potassium dichromate(VI) solution acidified with dilute sulphuric acid.


Note:  The equation for this is rather complicated for this introductory page. If you are interested, you will find a similar example (ethanol to ethanoic acid) on the page dealing with writing equations for redox reactions.


Ethanal can also be reduced back to ethanol again by adding hydrogen to it. A possible reducing agent is sodium tetrahydridoborate, NaBH4. Again the equation is too complicated to be worth bothering about at this point.

An update on oxidising and reducing agents
  • Oxidising agents give oxygen to another substance or remove hydrogen from it.
  • Reducing agents remove oxygen from another substance or give hydrogen to it.

Oxidation and reduction in terms of electron transferThis is easily the most important use of the terms oxidation and reduction at A' level.
Definitions
  • Oxidation is loss of electrons.
  • Reduction is gain of electrons.
It is essential that you remember these definitions. There is a very easy way to do this. As long as you remember that you are talking about electron transfer:
A simple example
The equation shows a simple redox reaction which can obviously be described in terms of oxygen transfer.

Copper(II) oxide and magnesium oxide are both ionic. The metals obviously aren't. If you rewrite this as an ionic equation, it turns out that the oxide ions are spectator ions and you are left with:

A last comment on oxidising and reducing agents
If you look at the equation above, the magnesium is reducing the copper(II) ions by giving them electrons to neutralise the charge. Magnesium is a reducing agent.
Looking at it the other way round, the copper(II) ions are removing electrons from the magnesium to create the magnesium ions. The copper(II) ions are acting as an oxidising agent.
Warning!
This is potentially very confusing if you try to learn both what oxidation and reduction mean in terms of electron transfer, and also learn definitions of oxidising and reducing agents in the same terms.
Personally, I would recommend that you work it out if you need it. The argument (going on inside your head) would go like this if you wanted to know, for example, what an oxidising agent did in terms of electrons:
  • An oxidising agent oxidises something else.
  • Oxidation is loss of electrons (OIL RIG).
  • That means that an oxidising agent takes electrons from that other substance.
  • So an oxidising agent must gain electrons.
Or you could think it out like this:
  • An oxidising agent oxidises something else.
  • That means that the oxidising agent must be being reduced.
  • Reduction is gain of electrons (OIL RIG).
  • So an oxidising agent must gain electrons.
Understanding is a lot safer than thoughtless learnin

Tuesday, August 21, 2018

PRAY FOR KERALA

THE TIMES OF INDIA | AUG 21, 2018 , 12:53:34 IST

Kerala floods live updates: Over 10 lakh in relief camps; Centre declares disaster 'calamity of severe nature'

Kerala got some respite from rain on Monday but the state faces the huge task of rehabilitation. 223 deaths have been reported and 10.28 lakh people are staying in 3274 relief camps, of which more than one lakh are kids below 12 years of age, said chief minister Pinarayi Vijayan. Stay with us for all live updates.
Live Updates
FILTER UPDATES
10:42 PM (IST), Aug 20
According to geologist K R Jagadeesan, who inspected the areas, the cracks appeared due to heavy rain and the slopes of the locality. He said he would give a report to the District Collector, recommending further study by the Centre for Earth Science Studies.
10:18 PM (IST), Aug 20
Majority of the inmates in various relief camps in Chengannur said it was their second life and they had seen death very close in the form of flood waters.
10:07 PM (IST), Aug 20
No one will be allowed to distribute food or any other items directly to the relief camps. Everyone should donate the relief materials to the district administration or the people who are heading the camps
Kerala CM Pinarayi Vijayan
09:45 PM (IST), Aug 20
The huge drop in the figure bought cheers to the state as it is a clear indication that the worst crisis it had faced ever has been over.
09:14 PM (IST), Aug 20

In 3270 camps, 10.28 lakh people are staying of which 1 lakh are kids below 12 years of age, said chief minister Pinarayi Vijayan.

09:07 PM (IST), Aug 20

Fishermen who were involved in the rescue operations will be felicitated by the state government on August 29 at Thiruvananthapuram.

08:58 PM (IST), Aug 20

MPs of Lok Sabha and Rajya Sabha have been asked to contribute to Kerala relief works.

08:46 PM (IST), Aug 20

Reserve Bank of India has agreed to exchange all the currency notes that have been damaged in the flood-hit areas, said Kerala chief minister Pinarayi Vijayan.

08:41 PM (IST), Aug 20
Two consignments of 9 tonnes of ready-to-eat food have arrived at the Kochi-headquartered DRDO laboratory, Naval Physical and Oceanographic Laboratory (NPOL) and is being distributed to various places.
08:32 PM (IST), Aug 20
'THANKS', read the simple message in huge font in white paint on the terrace of a home, encapsulating sentiments of grateful Keralites rescued by defence personnel after raging floods left them marooned.
08:21 PM (IST), Aug 20
The Tamil Nadu government has launched a website called 'Anbudan Tamizhagam' to facilitate collection, transportation and distribution of supplies and funds to Kerala by engaging with the civil society in the state.
08:13 PM (IST), Aug 20
On Monday, 2059 persons who were staying in camps returned to home and 28 camps were closed. A total of 30684 persons of 8190 families are staying in remaining 127 camps. Among the total number of inmates 12082 are women and 6665 are children.
08:06 PM (IST), Aug 20

Commercial flight operations from the naval airport at Kochi commenced on Monday with the first Air India flight from Bengaluru arriving in the morning. Small aircrafts are being operated from the naval airport as the Kochi International Airport has shut operations till August 26 following flooding of the runways

Wednesday, August 8, 2018

CHEMISTERY------- COVALENT BOND

Covalent Bond Definition

A covalent bond is a chemical link between two atoms or ions where the electron pairs are shared between them. A covalent bond may also be termed a molecular bond. Covalent bonds form between two nonmetal atoms with identical or relatively close electronegativity values. This type of bond may also be found in other chemical species, such as radicals and macromolecules. The term "covalent bond" first came into use in 1939, although Irving Langmuir introduced the term "covalence" in 1919 to describe the number of electron pairs shared by neighboring atoms.
The electron pairs that participate in a covalent bond are called bonding pairs or shared pairs. Typically, sharing bonding pairs allows each atom to achieve a stable outer electron shell, similar to that seen in noble gas atoms.

Polar and Nonpolar Covalent Bonds

Two important types of covalent bonds are nonpolar or pure covalent bonds and polar covalent bonds. Nonpolar bonds occur when atoms equally share electron pairs. Since only identical atoms (same electronegativity as each other) truly engage in equal sharing, the definition is expanded to include covalent bonding between any atoms with an electronegativity difference less than 0.4. Examples of molecules with nonpolar bonds are H2, N2, and CH4.
As the electronegativity difference increases, the electron pair in a bond is more closely associated with one nucleus than the other. If the electronegativity difference is between 0.4 and 1.7, the bond is polar. If the electronegativity difference is greater than 1.7, the bond is ionic.

Covalent Bond Examples

There is a covalent bond between the oxygen and each hydrogen in a water molecule(H2O). Each of the covalent bonds contains two electrons - one from a hydrogen atom and one from the oxygen atom. Both atoms share the electrons.
A hydrogen molecule, H2, consists of two hydrogen atoms joined by a covalent bond. Each hydrogen atom needs two electrons to achieve a stable outer electron shell. The pair of electrons is attracted to the positive charge of both atomic nuclei, holding the molecule together.

Phosphorus can form either PCl3 or PCl5. In both cases, the phosphorus and chlorine atoms are connected by covalent bonds. PCl3 assumes the expected noble gas structure, where the atoms achieve complete outer electron shells. Yet PCl5 is also stable, so it's important to remember covalent bonds don't always abide by the octet rule.

Kourtney Kardashian

Kourtney Kardashian and Younes Bendjima have called it quits, a source confirms to PEOPLE, adding that “it didn’t end well.”
The news comes as photos of Bendjima getting cozy with another woman in Mexico on Monday surfaced on TMZ. On his Instagram story, Bendjima denied the situation was romantic, writing: “They really want me to be the bad guy. F— your Hollywood bulls—, can’t have fun with your friends no more.”
The couple was going strong as recently as last month, when they took a romantic European vacation joined in part by the three children she shares with ex Scott Disick: Mason, 8, Reign, 3, and Penelope, 5.
But tensions had been lingering over Kardashian’s social media activity. During the three-week trip, she posted multiple photos on Instagram showing off her toned physique in bathing suits, including two photos of her eating bread in a bikini while lounging on a yacht.
In a since-deleted comment on a photo of Kardashian, 39, wearing a thong bikini, Bendjima, 25, shaded the post, writing: “That’s what you need to show to get likes?”
A source later told PEOPLE Bendjima was never a fan of his girlfriend’s revealing shots.
“He never liked that she posted sexy pictures of herself on social media,” said the source. “He doesn’t want his girlfriend to do that. He gets that it’s her job, but wants her to post more covered-up pictures. He has always had a problem with this. This is the stuff they argue about and what made them split in the past.”

Tuesday, August 7, 2018

Karunanidhi's death

Chennai: Dravida Munnetra Kazhagam (DMK) chief M Karunanidhi passed away on Tuesday at the age of 94 after a prolonged illness. Kalaignar, as he was fondly called, breathed his last at 6:10 pm. The Kauvery Hospital had earlier in the evening said that the DMK chief's health condition had become "extremely critical and unstable". Karunanidhi was admitted to the Kauvery Hospital on July 28 following a drop in his blood pressure.
Hundreds of supporters were outside the Kauvery Hospital as the news of the DMK patriarch's death was announced in the evening. Al turned emotional with most of them started to cry. Earlier, the state DGP had ordered tightening of security across Tamil Nadu to maintain law and order situation.

Monday, August 6, 2018

Kerala temple priest arrested for threatening bomb attack at President Kovind function venue

Kerala temple priest arrested for threatening bomb attack at President Kovind function venue
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President Ram Nath Kovind is on a three-day visit to KeralaA temple priest was arrested for allegedly threatening to plant a bomb at St Thomas College here where President Ram Nath Kovind is scheduled to attend a function tomorrow, police said Monday.
At around 1 am last night, the man, who was in an inebriated state, called up the police control room in Kerala and threatened to plant a bomb at the college where the president would inaugurate the centenary celebrations Tuesday, they added.
Thrissur District Police chief Yatish Chandra said the accused, Jayaraman, was picked up after his mobile phone was tracked down. During interrogation, he admitted to having made the call in an inebriated state. He is a priest at the Chirakal Bhagavathy temple here. A case was registered against him for criminal intimidation, the police said.
The president, who was on a three-day visit to Kerala, arrived in the state capital yesterday. Kovind would be inaugurating a function at the Assembly complex in Thiruvananthapuram to mark the conclusion of the diamond jubilee celebrations of the Kerala Legislative Assembly today. Tomorrow, the president would also have breakfast with the chief justice and judges of the Kerala High Court at Kochi. He would offer prayers at the famed Guruvayur Sri Krishna temple before returning to Delhi on August 8

National Sisters Day 2018 – August 5

Maybe you have an older sister that you look to for guidance. Maybe you have a younger sister who is looking to you for inspiration. Whatever the circumstance, nothing can quite compare to the bond that sisters have. So on the first Sunday in August, let’s celebrate National Sisters Day — a day to recognize the sisters who make such a difference in our lives.

WHEN IS NATIONAL SISTERS DAY 2018?

National Sisters Day is celebrated on the first Sunday of August. In 2018 that means it falls on August 5. 

NATIONAL SISTERS DAY ACTIVITIES

1. Reach out
If you can't spend time with your sister in person, taking the time to call or send a card is the best gift you can give her.
2. Be a good listener
That means through good times and bad. Empathy and attention can go a long way.
3. Go on an adventure
Try something new together. What better way to bond with your sister than to push some boundaries.

WHY WE LOVE NATIONAL SISTERS DAY

A. It's a time to fix any misunderstandings
Arguments happen. So take this day to reconnect if necessary. Because it's going to feel great when you can "hug it out" again.
B. No sister? No problem
While it may seem like National Sisters Day is only for people who have biological sisters, your best friend can be just as close. Treat her like a sister!
C. Cherish the memories
Life is busy, but use National Sisters Day as the opportunity to go through your old photos (and videos) and remember the good times. Then, make plans to go somewhere fun and do it all again.